Nga 1863 tannatuuka, silikoni yonna-ebirungo ebirimu ebimanyiddwa era ebikozesebwa abantu byali bikozesebwa bya silikoni ebitali biramu, omuli silikoni ow’obutonde -byakyusibwamu ebintu eby’omulembe nga ceramic, seminti, ne ndabirwamu. Mu 1863, abakugu mu by’eddagala mu Bufalansa C. Feidedel ne JM raft synthesized tetraethyl silane nga bakozesa enkola ya ethyl zinc ne silicon tetrafluoride mu ttanka esibiddwa. Yali compound ya organosilicon esoose mu byafaayo. Kino nakyo kyatandikawo ekirungo kya organosilicon.
Okuva olwo, abakugu mu by’eddagala baali bagenda mu maaso n’okugatta ebirungo ebipya ebya organosilicon. Mu byo, kirungi okwogera ku A. Lamenberg, ekozesa ethyl orthosilicate okukyusa silicon tetrachloride era n’ekolagana ne alkyl zinc okufuna ebirungo bya organosilicon ne mono -, ii -, ne III silicon functionals, ne A.polis, synthesizes the first all{{5Lsilsilsiltz. Mu myaka 40 okutuuka mu 1903, wadde nga tewali bituukiddwaako mu tekinologiya ebyatumbula ddala enkulaakulana ya silikoni byakolebwa, abakugu mu by’eddagala baakola nnyo emirimu egy’okutandikawo mu kiseera kino. N’olwekyo, omutendera guno guyinza okutwalibwa ng’ekiseera eky’okutandikawo silikoni.
Omukugu mu by’eddagala ow’ettutumu ow’e Bungereza FSkipping atwalibwa ng’omutandisi wa Organosilicon Chemistry. Okuva mu 1898 okutuuka mu 1944, yakola okunoonyereza okunene era mu - okw’obwegendereza mu mulimu guno era n’afulumya obutasalako empapula 51 ezikwatagana mu Journal of the Chemical Society of the United Kingdom.
Mu 1904, W n’omusawo w’eby’obutonde Omugirimaani Dithey baakizuula mu bwetwaze nti ebirungo bya organosilicon bisobola okusengekebwa okuyita mu nkola ya Grignard. Enkola eno yalongoosebwa nnyo ku kyuma eky’emabega-enkola z’okusengejja organic olw’obwangu bw’okukola, amakungula amangi, ekifo ekinene eky’okukozesa n’obukuumi obw’amaanyi. Enkola eno esobola okukozesebwa okugatta ebirungo eby’enjawulo ebya organosilicon ebirina enkola za silicon ez’enjawulo .
KIP-Ping yasengeka omuwendo omunene ogw'oluzzi-ebirungo bya organosilicon ebitegeezeddwa nga tukozesa enkola eno. Enkola eno yafuuka omusingi gw’amakolero ga organosilicon mu biseera eby’omu maaso, era esigala nga y’emu ku nkola ezisinga obukulu ez’okugatta organosilicon leero. RMGCL+SICL- rsicl:+rSicl+R:sic1+ RSI +MGCL,(2.3)Okukuba organochlorosilanes ezikoleddwa nga tukozesa enkola ya Grignard reagent era ne bakizuula nti zisobola okufumbirwa mu mazzi okukola sililoni. Mu kiseera kye kimu, era yakiraba nti silanediol ne siltriol bisobola okwongera okuyita mu kusengejja okw’omunda okukola polimeeri. Wabula ng’omukugu mu by’obutonde (organic chemist), teyafaayo ku nkola eno n’akatono era n’atuuka n’okukyawa ebintu bino ebya polimeeri. N’olwekyo, teyazisoma. Mu nsonga eno, Dilthey yakola omulimu ogw’amakulu: yafukirira diphenylsilanediol okufuna hexaphenylcyclotrisiloxane. Kino kye kirungo kya cyclic polysiloxane ekisoose okuloopebwa mu byafaayo. Ye mutandisi mu kusengejja linear silicon-oxane, era okujja kwayo kukoze kinene nnyo mu kutumbula enkulaakulana ya organosilicon polymers.
Okuva mu 1904 okutuuka mu 1937, bannassaayansi tebakoma ku kukola bikozesebwa bingi ebyangu eby’ekirungo kya organosilicon wabula baakola era ne bakola ensengekera za cyclic ne linear polysiloxysaccharides. Okugatta ku ekyo, A.Stock ezudde silanhydrides nnyingi mu kunoonyereza okusookerwako era etandise okusengejja ebirungo bya atomu za silikoni ezitali za asymmetric. Emyaka amakumi asatu egiyise gibadde kiseera kya kukula kwa organosilicon chemistry.
Oluvannyuma lw’emyaka gya 1930 abakugu mu by’eddagala baatandika okutegeera essuubi ly’okukozesa ery’ebirungo bya organosilicon ebya waggulu-. Abanoonyereza abaasooka mu mulimu guno kuliko JFHYDE OF corning glass company mu Amerika, WJ Petnode ne Egrochow of General Electric (GE) mu Amerika, ne KA y’eyali Soviet Union Andrianov ne Bndolgov, R. Miller okuva mu Germany, etc
Hyde, okwawukana ku ndowooza ya Kipping, ye yasooka okugatta organosilicon chemistry ne polymer chemistry. Wansi w’obulagirizi bwe, Corning Inc. yakola silikoni resins, coatings, impregnaging agents n’ebintu ebirala bingi ebya polyorganosiloxane ku lugoye lw’endabirwamu oluziyiza amasannyalaze. Mu kiseera kye kimu, dowchemicals za Amerika era zaatandika okunoonyereza ku kukola polyorganosiloxanes n’okutandikawo ebimera ebigezesa eby’amafuta ga dimethyl silicone ne methyl phenyl silicone resin mu 1942. Mu kiseera ekyo, organochlorosilane monomers zaali zisinga kusengekebwa mu nkola ya Grignard, kale supply ya monomers yafuuka monomers okukosa enzirukanya y’emirimu mu nkola ya main developments. Mu 1940, Rochow yayiiya "enkola y'okusengejja obutereevu" eya methylsilane era n'asaba patent. Enkola eno tekozesa solvents. Ye ggaasi-ensengekera ya phase ennywevu (solid phase reaction) nga chloromethane ayingizibwa butereevu mu butto wa silikoni alimu ekirungo ekiziyiza ekikomo (Equation 2.4). Mu kiseera kino kyennyini, omukugu mu by’eddagala Omugirimaani Muller naye yasaba patent efaananako bwetyo, naye olunaku lw’okukulembeza lwali wayiseewo emyezi mwenda okusinga egya Rochow. Omugabo guno ogw’enjawulo guleetedde enkyukakyuka ey’amaanyi mu kukola silikoni n’okutumbula okwongera okutumbula amakolero ga silikoni.
Mu 1943, kkampuni ya Dow Chemical Company ne Corning Inc. baatandikawo ensi yonna -Kkampuni ya Silicone Professional Company emanyiddwa ennyo - Dow Corning Corporation, era mu mwaka gwe gumu, ekkolero erikola polyorganosiloxanes lyazimbibwa mu Mdand, Michigan, USA. Kkampuni eno mu bbanga ttono yakola ekintu ekisiba omuliro ekya DC#4 era n’ekozesa bulungi ennyonyi eziri waggulu-obugulumivu. Oluvannyuma, kkampuni eno yakola ebika bingi ebya silikoni resin, ebizigo, amafuta agaziyiza ensisi, amafuta agasiiga, defoamers n’ebintu ebirala. Mu 1947, General Electric Company era yatandikawo ekitongole kya Organosilicon Division, ekyafulumya ekirungo kya organosilicon mu nkola eno obutereevu era ne kivaamu ebintu bya polysiloxane. Tekinologiya w’okufulumya kkampuni ya General Electric Company yatwalibwa amakolero ga silikoni agaddirira.
Okunoonyereza mu kitundu kya silicone polymers mu Soviet Union kwali kwa njawulo nnyo naddala Andrianov. Ng’oggyeeko okukola omulimu mungi ku polysiloxane polymers n’okukola organosilicon polymers nnyingi ezirina omuwendo gw’okukozesa ogw’omugaso, era yaleeta ebintu ebirala nga boron, aluminium, titanium, tin ne phosphorus mu nsengekera ya polysiloxane okukyusa. Era ye muntu eyasooka okukozesa Silazane ng’ekizigo ekiziyiza amazzi.
Oluvannyuma lwa Ssematalo II okuggwa, olw’okukozesa obulungi ebintu bya silikoni mu kukola amagye, amakolero ga silikoni gaakulaakulana mangu nnyo era okufulumya kwago byonna byatandika ekkubo erya bulijjo. Mu myaka gya 1950, amakampuni agakola ebintu bya silikoni gaatandikibwawo mu lunyiriri mu nsi ez’enjawulo. Ebintu eby’enjawulo ebya silicone polymer, nga silikoni (nga mw’otwalidde-ebbugumu ewonya omupiira, ebbugumu ly’ekisenge ekiwujjo, omupiira gwa silikoni omutangaavu, amafuta-okuziyiza fluorosilicone, n’ebirala), amafuta ga diffusion pump, laminating resin, silicone emulsion, silicone surfalant Oluvannyuma lw’omulala.
wakati wa 1938 ne 1965, mu ndowooza n’okukozesa; Organosilicon chemistry ekola enkulaakulana ey’amangu mu monomera ne polimeeri. Wano, ensonga enkulu ezirina okuggumiza mulimu: silicylation reactions, hydrosilylation reactions, okunoonyereza ku photoactive organosilicon compounds, synthesis of organosilicon compounds containing carbon functional groups, okunoonyereza ku nkola z’enkola, okulongoosa enkola z’okukola polymerization, awamu n’okuvaayo okuddirira okwali okubuusabuusa kuno okwali kwa silika, ne silicone rubber, ne coupling agents, etc.
Okuva mu 1965, ng’oggyeeko okugatta, okukulaakulanya, okulongoosa n’okukozesa ebituukiddwaako ebiriwo, abantu nabo bakyukidde mu kitundu ekipya ekya organosilicon chemistry. Mu byo, eby’amaanyi mulimu: organosilicon stereochemistry, ebirungo bya organosilicon ebirina emirimu gy’omubiri, cyclic ne linear polysilanes, silicon ez’enjawulo-ezirimu ensengekera wakati, ebirungo bya bond ebitali binywevu ebya silicon, ebirungo by’empeta eby’ekika kya ternade, silikoni, silikoni {3}okukwatagana kw’ebiyungo bya ttaniyani, ekirungo kya polisironi, silikoni, silikoni {3}okukwatagana kw’ebiyungo bya ttaniyamu, ebirungo ebiziyiza ebirungo ebiziyiza, silikoni, silikoni {3}okukwatagana kw’ebiyungo bya bbaasa, silikoni, silikoni, silikoni {3}, ebirungo ebiziyiza ebirungo ebiziyiza, silikoni, silikoni, silikoni {3}. Sesquiloxanes, silicon-zirimu dendritic ne hyperbranched polymer compounds, n’ebirala Mu makolero ga silicone, ekipimo ky’okufulumya silicone monomers ne polymers buli kiseera kigaziwa, tekinologiya w’okufulumya alongoosa buli kiseera, era ssente z’okufulumya zikendeera buli kiseera. Kino kifuula ebintu bya silikoni okuvuganya. Enkulaakulana egenda mu maaso eya multi-ekola era nga ya waggulu-ebiva mu kukola silikoni, gamba nga polysiloxanes ez’obujjanjabi, ezitambuza n’eziyisa ebbugumu, egaziyizza obutasalako obuwanvu bwabyo obw’okukozesa. Ebintu ebikolebwa mu silikoni buli kiseera biyingira mu bintu eby’enjawulo eby’ebyenfuna by’eggwanga mu ngeri enkulu nga silicone oil, silicone rubber, silicone resin, ne silone coupling agents.